Sublingual refers to a method of administering substances via the mouth in such a way that the substances are rapidly absorbed via the blood vessels under the tongue (the buccal mucosa) rather than via the digestive tract.
Sublingual absorption is generally much faster: Nutrients absorbed sublingually enter the bloodstream directly and can start working within minutes.
Sublingual absorption is generally more efficient: sublingually absorbed nutrition avoids exposure to the gastric system and liver, so that more of an administered dose is absorbed.
The mint you have in your mouth is working on the cigarette you just smoked!